Potassium nitrate Solution Preparation

How many grams of potassium nitrate to weigh for any molarity and volume, with a full recipe table.

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To prepare a solution of potassium nitrate you need the grams, and grams is molarity × volume in litres × 101.1023 g/mol. A litre of 1 M takes 101.1023 g; 500 mL of 0.1 M takes 5.0551 g; 250 mL of 0.01 M takes 252.76 mg. Enter the strength you want and the volume you want it in, and the calculator returns the mass to weigh together with the same figure in milligrams and as a percentage strength.

The figure comes from the formula. Potassium nitrate is 39.0983 (K) + 14.007 (N) + 3 × 15.999 (O), which is 101.1023 g/mol, taking standard atomic weights, and every page here computes that sum rather than quoting it. Oxygen makes up the largest share of the mass: 3 of the 5 atoms in a formula unit are oxygen, and they account for 47.997 g of the 101.1023 g, or 47.47% by mass. The derivation table below breaks the whole molecule down element by element.

Order of operations matters more than precision here. Dissolve the solid in rather less than the final volume, then make up to the mark once it has all gone into solution and come back to room temperature — warm solutions read low when they cool. If the calculated mass is under about 20 mg, prepare ten times the strength and dilute it tenfold by pipette instead, because C₁V₁ = C₂V₂ carries less error than a marginal weighing.

Saltpetre — a fertiliser, a curing salt and the oxidiser in black powder. Its solubility climbs steeply with temperature, which is how it is purified. At 101.1023 g/mol it is heavier than 10 of the 34 salts covered here, and that ranking matters more than it looks: calcium carbonate has a molar mass of 100.086 g/mol, so a gram of it contains 1.02% more formula units than a gram of potassium nitrate. Weigh by mass and you are not weighing equal amounts of substance.

Two practical things move the result. Purity below 100% means the weighed mass overstates how much compound you have — at 98% assay, 2.022 g of every 101.1023 g is not the compound — and any water picked up from the air does the same. Both are systematic, so they shift every solution made from that jar in the same direction.

The formula

m = c × (V ÷ 1000) × 101.1023
c
The molarity you want, in mol/L
V
The volume you want to make, in millilitres
101.1023
The molar mass of potassium nitrate in g/mol, derived from its formula
m
The mass of potassium nitrate to weigh out, in grams

How it works, step by step

  1. Enter the molarity you want, in mol/L.
  2. Enter the volume you want to make, in millilitres.
  3. The two are multiplied together and by 101.1023 g/mol.
  4. The result is the mass to weigh; dissolve it in part of the volume and then make up to the mark.

Worked examples

250 mL of 0.1 M potassium nitrate

Weigh 2.52756 g. That is 0.1 M × 0.25 L × 101.1023 g/mol, and it comes to 2527.56 mg if your balance is set to milligrams. Dissolve in about 175 mL first, then make up to 250 mL.

500 mL of 0.5 M potassium nitrate

Weigh 25.2756 g. That is 0.5 M × 0.5 L × 101.1023 g/mol, and it comes to 25,275.6 mg if your balance is set to milligrams. Dissolve in about 350 mL first, then make up to 500 mL.

1000 mL of 1 M potassium nitrate

Weigh 101.102 g. That is 1 M × 1 L × 101.1023 g/mol, and it comes to 101,102 mg if your balance is set to milligrams. Dissolve in about 700 mL first, then make up to 1000 mL.

How to read your score

0–0NothingNothing to weigh.
0–0.05Below a sensible weighingUnder 50 mg. Weigh ten or a hundred times this and dilute; the balance error does not shrink with the sample.
0.05–10Weighable directlyFrom 50 mg to 10 g, which is where a two- or three-decimal balance gives better than 1% on the mass.
10–—Large batchMore than 10 g of potassium nitrate. Worth checking solubility and, for a solid that generates heat on dissolving, adding it in portions.

Frequently asked questions

What is the molar mass of potassium nitrate (KNO3)?

It is 101.1023 g/mol. That is the sum of the standard atomic weights of every atom in the formula: 39.0983 (K) + 14.007 (N) + 3 × 15.999 (O). One mole of potassium nitrate therefore weighs 101.1023 g, and a gram of it is 9.891 mmol.

What percentage of potassium nitrate is oxygen?

47.47% by mass. Each formula unit contains 3 oxygen atoms contributing 47.997 g of the 101.1023 g total, so 100 g of potassium nitrate contains 47.47 g of oxygen and a kilogram contains 474.74 g of it.

How much potassium nitrate do I need for 1 litre of 1 M solution?

101.1023 g — the molar mass in grams, which is what a 1 molar solution means. For 1 L of 0.1 M it is 10.1102 g, and for 1 L of 0.01 M it is 1.01102 g.

How much for 100 mL of 0.1 M?

1.01102 g. The volume is a tenth of a litre and the strength a tenth of molar, so the mass is a hundredth of 101.1023 g. In milligrams that is 1011.02 mg.

Do I dissolve the solid first or make up the volume first?

Dissolve first, in perhaps 70% of the final volume, then make up to the mark. Adding solid to a full flask overshoots the volume and leaves the solution weak, and undissolved solid at the mark means the strength keeps changing as it goes in.

Can I dilute a stock solution instead of weighing?

Yes, and it is more accurate for small amounts. C₁V₁ = C₂V₂: to get 500 mL of 0.01 M from a 0.5 M stock, take 10 mL of stock and make up to 500 mL. Weighing the 505.51 mg that 500 mL of 0.01 M needs directly is the harder of the two.

Solution recipes for potassium nitrate

How the molar mass of potassium nitrate is arrived at
ElementAtomsAtomic weightContribution (g/mol)By mass
Oxygen (O)315.99947.99747.47%
Potassium (K)139.098339.098338.67%
Nitrogen (N)114.00714.00713.85%
Total — one mole of potassium nitrate101.1023100%

Standard atomic weights, IUPAC 2021. The contribution column is atoms × atomic weight, and the total is the molar mass this page uses: 101.1023 g/mol.

Grams of potassium nitrate needed for a standard solution
Targetfor 100 mLfor 250 mLfor 500 mLfor 1 L
0.001 M10.1102 mg25.2756 mg50.5511 mg101.102 mg
0.005 M50.5511 mg126.378 mg252.756 mg505.512 mg
0.01 M101.102 mg252.756 mg505.512 mg1.01102 g
0.05 M505.512 mg1.26378 g2.52756 g5.05512 g
0.1 M1.01102 g2.52756 g5.05512 g10.1102 g
0.15 M1.51653 g3.79134 g7.58267 g15.1653 g
0.2 M2.02205 g5.05512 g10.1102 g20.2205 g
0.25 M2.52756 g6.31889 g12.6378 g25.2756 g
0.5 M5.05511 g12.6378 g25.2756 g50.5511 g
1 M10.1102 g25.2756 g50.5511 g101.102 g
2 M20.2205 g50.5511 g101.102 g202.205 g

Each cell is molarity × volume in litres × 101.1023 g/mol. Dissolve the solid first and then make up to the marked volume — adding solid to a full volume overshoots it.

Potassium nitrate among other salts, by molar mass
CompoundFormulaMolar mass (g/mol)Millimoles in 1 g
Sodium nitrateNaNO384.9937711.766
Magnesium chlorideMgCl295.20510.504
Calcium carbonateCaCO3100.0869.9914
Potassium nitrate (this page)KNO3101.10239.891
Sodium carbonateNa2CO3105.98759.4351
Calcium chlorideCaCl2110.9789.0108
Magnesium sulfateMgSO4120.3618.3083

Ordered by molar mass. The last column is 1000/M, which is the number a weighed gram actually gives you.

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