Silver nitrate Solution Preparation

How many grams of silver nitrate to weigh for any molarity and volume, with a full recipe table.

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To prepare a solution of silver nitrate you need the grams, and grams is molarity × volume in litres × 169.8722 g/mol. A litre of 1 M takes 169.8722 g; 500 mL of 0.1 M takes 8.4936 g; 250 mL of 0.01 M takes 424.68 mg. Enter the strength you want and the volume you want it in, and the calculator returns the mass to weigh together with the same figure in milligrams and as a percentage strength.

The figure comes from the formula. Silver nitrate is 107.868 (Ag) + 14.007 (N) + 3 × 15.999 (O), which is 169.8722 g/mol, taking standard atomic weights, and every page here computes that sum rather than quoting it. Silver makes up the largest share of the mass: 1 of the 5 atoms in a formula unit is silver, and they account for 107.868 g of the 169.8722 g, or 63.5% by mass. The derivation table below breaks the whole molecule down element by element.

Order of operations matters more than precision here. Dissolve the solid in rather less than the final volume, then make up to the mark once it has all gone into solution and come back to room temperature — warm solutions read low when they cool. If the calculated mass is under about 20 mg, prepare ten times the strength and dilute it tenfold by pipette instead, because C₁V₁ = C₂V₂ carries less error than a marginal weighing.

The reagent for chloride tests and the silver source in mirroring and photography. Solutions darken in light and stain skin permanently. At 169.8722 g/mol it is heavier than 23 of the 34 salts covered here, and that ranking matters more than it looks: potassium iodide has a molar mass of 166.0028 g/mol, so a gram of it contains 2.33% more formula units than a gram of silver nitrate. Weigh by mass and you are not weighing equal amounts of substance.

Two practical things move the result. Purity below 100% means the weighed mass overstates how much compound you have — at 98% assay, 3.3974 g of every 169.8722 g is not the compound — and any water picked up from the air does the same. Both are systematic, so they shift every solution made from that jar in the same direction.

The formula

m = c × (V ÷ 1000) × 169.8722
c
The molarity you want, in mol/L
V
The volume you want to make, in millilitres
169.8722
The molar mass of silver nitrate in g/mol, derived from its formula
m
The mass of silver nitrate to weigh out, in grams

How it works, step by step

  1. Enter the molarity you want, in mol/L.
  2. Enter the volume you want to make, in millilitres.
  3. The two are multiplied together and by 169.8722 g/mol.
  4. The result is the mass to weigh; dissolve it in part of the volume and then make up to the mark.

Worked examples

250 mL of 0.1 M silver nitrate

Weigh 4.24681 g. That is 0.1 M × 0.25 L × 169.8722 g/mol, and it comes to 4246.81 mg if your balance is set to milligrams. Dissolve in about 175 mL first, then make up to 250 mL.

500 mL of 0.5 M silver nitrate

Weigh 42.4681 g. That is 0.5 M × 0.5 L × 169.8722 g/mol, and it comes to 42,468.1 mg if your balance is set to milligrams. Dissolve in about 350 mL first, then make up to 500 mL.

1000 mL of 1 M silver nitrate

Weigh 169.872 g. That is 1 M × 1 L × 169.8722 g/mol, and it comes to 169,872 mg if your balance is set to milligrams. Dissolve in about 700 mL first, then make up to 1000 mL.

How to read your score

0–0NothingNothing to weigh.
0–0.05Below a sensible weighingUnder 50 mg. Weigh ten or a hundred times this and dilute; the balance error does not shrink with the sample.
0.05–10Weighable directlyFrom 50 mg to 10 g, which is where a two- or three-decimal balance gives better than 1% on the mass.
10–—Large batchMore than 10 g of silver nitrate. Worth checking solubility and, for a solid that generates heat on dissolving, adding it in portions.

Frequently asked questions

What is the molar mass of silver nitrate (AgNO3)?

It is 169.8722 g/mol. That is the sum of the standard atomic weights of every atom in the formula: 107.868 (Ag) + 14.007 (N) + 3 × 15.999 (O). One mole of silver nitrate therefore weighs 169.8722 g, and a gram of it is 5.8868 mmol.

What percentage of silver nitrate is silver?

63.5% by mass. Each formula unit contains 1 silver atom contributing 107.868 g of the 169.8722 g total, so 100 g of silver nitrate contains 63.5 g of silver and a kilogram contains 635 g of it.

How much silver nitrate do I need for 1 litre of 1 M solution?

169.8722 g — the molar mass in grams, which is what a 1 molar solution means. For 1 L of 0.1 M it is 16.9872 g, and for 1 L of 0.01 M it is 1.69872 g.

How much for 100 mL of 0.1 M?

1.69872 g. The volume is a tenth of a litre and the strength a tenth of molar, so the mass is a hundredth of 169.8722 g. In milligrams that is 1698.72 mg.

Do I dissolve the solid first or make up the volume first?

Dissolve first, in perhaps 70% of the final volume, then make up to the mark. Adding solid to a full flask overshoots the volume and leaves the solution weak, and undissolved solid at the mark means the strength keeps changing as it goes in.

Can I dilute a stock solution instead of weighing?

Yes, and it is more accurate for small amounts. C₁V₁ = C₂V₂: to get 500 mL of 0.01 M from a 0.5 M stock, take 10 mL of stock and make up to 500 mL. Weighing the 849.36 mg that 500 mL of 0.01 M needs directly is the harder of the two.

Solution recipes for silver nitrate

How the molar mass of silver nitrate is arrived at
ElementAtomsAtomic weightContribution (g/mol)By mass
Silver (Ag)1107.8682107.868263.5%
Oxygen (O)315.99947.99728.25%
Nitrogen (N)114.00714.0078.246%
Total — one mole of silver nitrate169.8722100%

Standard atomic weights, IUPAC 2021. The contribution column is atoms × atomic weight, and the total is the molar mass this page uses: 169.8722 g/mol.

Grams of silver nitrate needed for a standard solution
Targetfor 100 mLfor 250 mLfor 500 mLfor 1 L
0.001 M16.9872 mg42.4681 mg84.9361 mg169.872 mg
0.005 M84.9361 mg212.34 mg424.681 mg849.361 mg
0.01 M169.872 mg424.681 mg849.361 mg1.69872 g
0.05 M849.361 mg2.1234 g4.24681 g8.49361 g
0.1 M1.69872 g4.24681 g8.49361 g16.9872 g
0.15 M2.54808 g6.37021 g12.7404 g25.4808 g
0.2 M3.39744 g8.49361 g16.9872 g33.9744 g
0.25 M4.24681 g10.617 g21.234 g42.4681 g
0.5 M8.49361 g21.234 g42.4681 g84.9361 g
1 M16.9872 g42.4681 g84.9361 g169.872 g
2 M33.9744 g84.9361 g169.872 g339.744 g

Each cell is molarity × volume in litres × 169.8722 g/mol. Dissolve the solid first and then make up to the marked volume — adding solid to a full volume overshoots it.

Silver nitrate among other salts, by molar mass
CompoundFormulaMolar mass (g/mol)Millimoles in 1 g
Iron(III) chlorideFeCl3162.1956.1654
Trisodium phosphateNa3PO4163.93916.0998
Potassium iodideKI166.00286.024
Silver nitrate (this page)AgNO3169.87225.8868
GypsumCaSO4·2H2O172.1645.8084
Potassium sulfateK2SO4174.25265.7388
Epsom saltMgSO4·7H2O246.4664.0574

Ordered by molar mass. The last column is 1000/M, which is the number a weighed gram actually gives you.

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