Epsom salt Percent Solution Calculator

Grams of Epsom salt for any % w/v strength, with the molarity and mg/mL equivalents.

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Percentage strength for Epsom salt is read as % w/v: grams of solute in 100 mL of solution. So 1% is 1 g per 100 mL, which for this compound works out at 0.040574 mol/L, and 0.9% is 9 g per litre or 0.036516 mol/L. The calculator takes a percentage and a volume and returns the grams to weigh, with the molarity and mg/mL equivalents beside it.

The figure comes from the formula. Epsom salt is 24.305 (Mg) + 32.06 (S) + 11 × 15.999 (O) + 14 × 1.008 (H), which is 246.466 g/mol, taking standard atomic weights, and every page here computes that sum rather than quoting it. Oxygen makes up the largest share of the mass: 11 of the 27 atoms in a formula unit are oxygen, and they account for 175.989 g of the 246.466 g, or 71.4% by mass. The derivation table below breaks the whole molecule down element by element.

Three different percentages are in circulation and they are not interchangeable. Per cent w/v is mass in a volume, the one used here and on medical labels; per cent w/w is mass in mass, the one on drums of concentrated reagent; per cent v/v is volume in volume, used for liquids mixed into liquids. For a dilute aqueous solution w/v and w/w are within a percent of each other, but for anything concentrated the density has to come into it.

Magnesium sulfate heptahydrate: bath salts, a magnesium source for plants, and a laboratory standard. Seven waters make it twice the weight per mole. At 246.466 g/mol it is heavier than 26 of the 34 salts covered here, and that ranking matters more than it looks: potassium sulfate has a molar mass of 174.2526 g/mol, so a gram of it contains 41.4% more formula units than a gram of Epsom salt. Weigh by mass and you are not weighing equal amounts of substance.

Watch which form you have. This page is the hydrate, MgSO4·7H2O, at 246.466 g/mol; the anhydrous salt is MgSO4 at 120.361 g/mol. The 126.105 g of water per mole is 51.17% of the weight, so weighing the hydrate as though it were anhydrous puts you 51.17% short on the compound itself. Suppliers sell both, and the label is the only way to tell them apart by eye.

The formula

m = p × V ÷ 100
p
The strength you want, as % w/v
V
The volume of solution, in millilitres
m
The mass of Epsom salt to weigh out, in grams
246.466
The molar mass of Epsom salt in g/mol, derived from its formula

How it works, step by step

  1. Enter the percentage strength you want, as % w/v.
  2. Enter the volume of solution in millilitres.
  3. Grams needed is percentage × volume ÷ 100, since 1% w/v is 1 g per 100 mL.
  4. The molarity that strength corresponds to for Epsom salt is shown beneath, using 246.466 g/mol.

Worked examples

0.9% w/v Epsom salt in 500 mL

0.9% w/v is 0.9 g per 100 mL, so 500 mL needs 4.5 g. In molar terms that solution is 0.036516 mol/L, and it is 9 mg/mL if you are dosing by volume.

5% w/v Epsom salt in 100 mL

5% w/v is 5 g per 100 mL, so 100 mL needs 5 g. In molar terms that solution is 0.20287 mol/L, and it is 50 mg/mL if you are dosing by volume.

10% w/v Epsom salt in 1000 mL

10% w/v is 10 g per 100 mL, so 1000 mL needs 100 g. In molar terms that solution is 0.40574 mol/L, and it is 100 mg/mL if you are dosing by volume.

How to read your score

0–0NothingNothing to weigh.
0–0.05Below a sensible weighingUnder 50 mg. Weigh ten or a hundred times this and dilute; the balance error does not shrink with the sample.
0.05–10Weighable directlyFrom 50 mg to 10 g, which is where a two- or three-decimal balance gives better than 1% on the mass.
10–—Large batchMore than 10 g of Epsom salt. Worth checking solubility and, for a solid that generates heat on dissolving, adding it in portions.

Frequently asked questions

What is the molar mass of Epsom salt (MgSO4·7H2O)?

It is 246.466 g/mol. That is the sum of the standard atomic weights of every atom in the formula: 24.305 (Mg) + 32.06 (S) + 11 × 15.999 (O) + 14 × 1.008 (H). One mole of Epsom salt therefore weighs 246.466 g, and a gram of it is 4.0574 mmol.

What percentage of Epsom salt is oxygen?

71.4% by mass. Each formula unit contains 11 oxygen atoms contributing 175.989 g of the 246.466 g total, so 100 g of Epsom salt contains 71.4 g of oxygen and a kilogram contains 714.05 g of it.

How many grams of Epsom salt make a 1% w/v solution?

1 g in 100 mL of solution, 5 g in 500 mL, 10 g in a litre. The percentage is fixed to the volume, not to the compound, so those masses are the same whatever is being dissolved — what changes with the compound is the molarity they come to.

What molarity is a 1% w/v solution of Epsom salt?

0.0405735 mol/L, because 1% w/v is 10 g/L and 246.466 g/L is one molar. A 0.9% solution is 0.036516 mol/L and a 5% solution is 0.20287 mol/L.

Is % w/v the same as % w/w?

No. Per cent w/v is grams per 100 mL of solution; per cent w/w is grams per 100 g of solution. They coincide only when the solution has a density of 1.00 g/mL, which dilute aqueous solutions approximately do and concentrated ones do not. Labels on concentrated reagents are usually w/w.

What is 1% w/v in mg/mL?

10 mg/mL, since 1 g in 100 mL is 1000 mg in 100 mL. For Epsom salt that is also 40.574 mmol/L, which is the form a dose calculation usually wants.

Percentage strengths of Epsom salt

How the molar mass of Epsom salt is arrived at
ElementAtomsAtomic weightContribution (g/mol)By mass
Oxygen (O)1115.999175.98971.4%
Sulfur (S)132.0632.0613.01%
Magnesium (Mg)124.30524.3059.861%
Hydrogen (H)141.00814.1125.726%
Total — one mole of Epsom salt246.466100%

Standard atomic weights, IUPAC 2021. The contribution column is atoms × atomic weight, and the total is the molar mass this page uses: 246.466 g/mol.

Percentage strengths of Epsom salt in grams and mol/L
Strengthper 100 mLper 500 mLper 1 LMolarity (mol/L)
0.1% w/v100 mg500 mg1 g0.0040574
0.25% w/v250 mg1.25 g2.5 g0.010143
0.5% w/v500 mg2.5 g5 g0.020287
0.9% w/v900 mg4.5 g9 g0.036516
1% w/v1 g5 g10 g0.040574
2% w/v2 g10 g20 g0.081147
3% w/v3 g15 g30 g0.12172
5% w/v5 g25 g50 g0.20287
10% w/v10 g50 g100 g0.40574
20% w/v20 g100 g200 g0.81147

A 1% w/v solution is 1 g in 100 mL, which for this compound is 0.040574 mol/L because 10 g/L divided by 246.466 g/mol gives that figure.

Epsom salt among other salts, by molar mass
CompoundFormulaMolar mass (g/mol)Millimoles in 1 g
Silver nitrateAgNO3169.87225.8868
GypsumCaSO4·2H2O172.1645.8084
Potassium sulfateK2SO4174.25265.7388
Epsom salt (this page)MgSO4·7H2O246.4664.0574
Sodium thiosulfate pentahydrateNa2S2O3·5H2O248.17154.0295
Copper(II) sulfate pentahydrateCuSO4·5H2O249.6774.0052
Sodium citrateNa3C6H5O7258.06833.8749

Ordered by molar mass. The last column is 1000/M, which is the number a weighed gram actually gives you.

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