Ethanol Percent Solution Calculator

Grams of ethanol for any % w/v strength, with the molarity and mg/mL equivalents.

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Percentage strength for ethanol is read as % w/v: grams of solute in 100 mL of solution. So 1% is 1 g per 100 mL, which for this compound works out at 0.21707 mol/L, and 0.9% is 9 g per litre or 0.19536 mol/L. The calculator takes a percentage and a volume and returns the grams to weigh, with the molarity and mg/mL equivalents beside it.

The figure comes from the formula. Ethanol is 2 × 12.011 (C) + 6 × 1.008 (H) + 15.999 (O), which is 46.069 g/mol, taking standard atomic weights, and every page here computes that sum rather than quoting it. Carbon makes up the largest share of the mass: 2 of the 9 atoms in a formula unit are carbon, and they account for 24.022 g of the 46.069 g, or 52.14% by mass. The derivation table below breaks the whole molecule down element by element.

Three different percentages are in circulation and they are not interchangeable. Per cent w/v is mass in a volume, the one used here and on medical labels; per cent w/w is mass in mass, the one on drums of concentrated reagent; per cent v/v is volume in volume, used for liquids mixed into liquids. For a dilute aqueous solution w/v and w/w are within a percent of each other, but for anything concentrated the density has to come into it.

Drinking alcohol and a solvent. Strength is quoted as percent by volume, and because ethanol is less dense than water that is not percent by weight. At 46.069 g/mol it is heavier than 1 of the 21 organic compounds covered here, and that ranking matters more than it looks: methanol has a molar mass of 32.042 g/mol, so a gram of it contains 43.8% more formula units than a gram of ethanol. Weigh by mass and you are not weighing equal amounts of substance.

Two practical things move the result. Purity below 100% means the weighed mass overstates how much compound you have — at 98% assay, 0.92138 g of every 46.069 g is not the compound — and any water picked up from the air does the same. Both are systematic, so they shift every solution made from that jar in the same direction.

The formula

m = p × V ÷ 100
p
The strength you want, as % w/v
V
The volume of solution, in millilitres
m
The mass of ethanol to weigh out, in grams
46.069
The molar mass of ethanol in g/mol, derived from its formula

How it works, step by step

  1. Enter the percentage strength you want, as % w/v.
  2. Enter the volume of solution in millilitres.
  3. Grams needed is percentage × volume ÷ 100, since 1% w/v is 1 g per 100 mL.
  4. The molarity that strength corresponds to for ethanol is shown beneath, using 46.069 g/mol.

Worked examples

0.9% w/v ethanol in 500 mL

0.9% w/v is 0.9 g per 100 mL, so 500 mL needs 4.5 g. In molar terms that solution is 0.19536 mol/L, and it is 9 mg/mL if you are dosing by volume.

5% w/v ethanol in 100 mL

5% w/v is 5 g per 100 mL, so 100 mL needs 5 g. In molar terms that solution is 1.0853 mol/L, and it is 50 mg/mL if you are dosing by volume.

10% w/v ethanol in 1000 mL

10% w/v is 10 g per 100 mL, so 1000 mL needs 100 g. In molar terms that solution is 2.1707 mol/L, and it is 100 mg/mL if you are dosing by volume.

How to read your score

0–0NothingNothing to weigh.
0–0.05Below a sensible weighingUnder 50 mg. Weigh ten or a hundred times this and dilute; the balance error does not shrink with the sample.
0.05–10Weighable directlyFrom 50 mg to 10 g, which is where a two- or three-decimal balance gives better than 1% on the mass.
10–—Large batchMore than 10 g of ethanol. Worth checking solubility and, for a solid that generates heat on dissolving, adding it in portions.

Frequently asked questions

What is the molar mass of ethanol (C2H6O)?

It is 46.069 g/mol. That is the sum of the standard atomic weights of every atom in the formula: 2 × 12.011 (C) + 6 × 1.008 (H) + 15.999 (O). One mole of ethanol therefore weighs 46.069 g, and a gram of it is 21.707 mmol.

What percentage of ethanol is carbon?

52.14% by mass. Each formula unit contains 2 carbon atoms contributing 24.022 g of the 46.069 g total, so 100 g of ethanol contains 52.14 g of carbon and a kilogram contains 521.44 g of it.

How many grams of ethanol make a 1% w/v solution?

1 g in 100 mL of solution, 5 g in 500 mL, 10 g in a litre. The percentage is fixed to the volume, not to the compound, so those masses are the same whatever is being dissolved — what changes with the compound is the molarity they come to.

What molarity is a 1% w/v solution of ethanol?

0.217066 mol/L, because 1% w/v is 10 g/L and 46.069 g/L is one molar. A 0.9% solution is 0.19536 mol/L and a 5% solution is 1.0853 mol/L.

Is % w/v the same as % w/w?

No. Per cent w/v is grams per 100 mL of solution; per cent w/w is grams per 100 g of solution. They coincide only when the solution has a density of 1.00 g/mL, which dilute aqueous solutions approximately do and concentrated ones do not. Labels on concentrated reagents are usually w/w.

What is 1% w/v in mg/mL?

10 mg/mL, since 1 g in 100 mL is 1000 mg in 100 mL. For ethanol that is also 217.07 mmol/L, which is the form a dose calculation usually wants.

Percentage strengths of ethanol

How the molar mass of ethanol is arrived at
ElementAtomsAtomic weightContribution (g/mol)By mass
Carbon (C)212.01124.02252.14%
Oxygen (O)115.99915.99934.73%
Hydrogen (H)61.0086.04813.13%
Total — one mole of ethanol46.069100%

Standard atomic weights, IUPAC 2021. The contribution column is atoms × atomic weight, and the total is the molar mass this page uses: 46.069 g/mol.

Percentage strengths of ethanol in grams and mol/L
Strengthper 100 mLper 500 mLper 1 LMolarity (mol/L)
0.1% w/v100 mg500 mg1 g0.021707
0.25% w/v250 mg1.25 g2.5 g0.054266
0.5% w/v500 mg2.5 g5 g0.10853
0.9% w/v900 mg4.5 g9 g0.19536
1% w/v1 g5 g10 g0.21707
2% w/v2 g10 g20 g0.43413
3% w/v3 g15 g30 g0.6512
5% w/v5 g25 g50 g1.0853
10% w/v10 g50 g100 g2.1707
20% w/v20 g100 g200 g4.3413

A 1% w/v solution is 1 g in 100 mL, which for this compound is 0.21707 mol/L because 10 g/L divided by 46.069 g/mol gives that figure.

Ethanol among other organic compounds, by molar mass
CompoundFormulaMolar mass (g/mol)Millimoles in 1 g
MethanolCH4O32.04231.209
Ethanol (this page)C2H6O46.06921.707
AcetoneC3H6O58.0817.218
UreaCH4N2O60.05616.651
Isopropyl alcoholC3H8O60.09616.64
Ethylene glycolC2H6O262.06816.111
GlycineC2H5NO275.06713.321

Ordered by molar mass. The last column is 1000/M, which is the number a weighed gram actually gives you.

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